Columnar self-assembly of rhomboid macrocyclic molecules via step-like intermolecular interaction. Crystal formation and gelation.
نویسندگان
چکیده
Two macrocyclic compounds with a rhomboid molecular shape, composed of a π-conjugated framework and an imine or amine functionality, were synthesized. The amine-containing macrocycle crystallizes with step-like interaction of each molecule, forming a columnar arrangement, although dispersion of the imine gelates upon ultrasonification.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 2 شماره
صفحات -
تاریخ انتشار 2012